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Material Safety Data Sheet Amine-Functional Aspartic Ester Resin
Part One Chemical and Company Identification
Chemical Code: F520
Chemical name: Polyaspartic Polyurea Resin
Company Name: Zhuhai Feiyang Novel Material Corporation Limited
Address: FEIYANG CHEMICAL FACTORY, BEIWU ROAD ,PETROL- CHEMICAL DISTRICT, ZHUHAI GAOLAN PORT ECONOMIC ZONE
Contact Tel.: 86-755-3669 4812 Fax: 86-755-3669 4828
Document No.: Sep-MSDS2012
Date into Effect: 12. 31st, 2011
Emergency Call: 86-755-3669 4812
Website: http://www.feiyang.com.cn
Part two ---Composition /component information
Component: Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Content[wt.-%]: 96%±2%
CAS No.: 136210-32-7
EINECS No.: 412-060-9
Index-No.: 607-350-00-9
GHS Classification: Skin Sens. 1 H317 Aquatic Chronic 4 H413
Fumaric acid diethyl ester
Content[wt.-%]: 0%-5%
CAS No.: 623-91-6
EINECS No.: 210-819-7
GHS Classification: Acute Tox. 4 Oral H302
Part three---Hazards identification
Classification of the substance or mixture
GHS Classification:
Sensitization of the skin, Category 1 (H317)
Chronically hazardous to the aquatic environment, Category 3 (H412)
Label elements
Hazardous components which must be listed on the label
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Identification no.: 607-350-00-9
GHS-Labelling
Warning
Hazard statements:
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P370 Advice for fire-fighters
P378 Suitable extinguishing media: Carbon dioxide (CO2), Foam, extinguishing powder. In cases of larger fires, water spray should be used. Don't use high volume water jet.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local regulation.
HAZARDOUS according to the criteria of NOHSC NON-DANGEROUS GOODS
Part four---First aid measure
Eye contact: eye contact immediately with water or saline irrigation water for at least 5 minutes, and the necessary medical observation.
Inhalation: speed away from the scene to fresh air. Keep the environment ventilation
Ingestion: Wash out mouth, vomiting. Seek medical advice
Part V: Fire-fighting measures
Hazardous characteristics: flammable.
Hazardous combustion products: carbon monoxide, carbon dioxide, oxides of nitrogen.
Fire fighting methods: fire extinguishing agent, extinguishing agents: water-resistant foam, dry powder, carbon dioxide, sand.
Part five ---fire fighting measures
Hazardous characteristics: flammable.
Hazardous combustion products: carbon monoxide, carbon dioxide, oxides of nitrogen.
Fire fighting methods: fire extinguishing agent, extinguishing agents: water-resistant foam, dry powder, carbon dioxide, sand.
Part six ----Accidental release measure
Products accidental spills: Eliminate all possible sources of ignition, such as flame, sparks. Evacuees from the area. Avoid breathing the gas and wear that can provide the required air respiratory equipment, respiratory masks can only use in the evacuation;
A small leak: sand or soil to absorb the overflow of the liquid, and then moved to a safe area, pending future disposal.
Large leak: sand or soil to prevent the spread of spilled liquids, such as overflow of liquid into the sewer, there is a potential danger of explosion or toxic; shall immediately notify the relevant authorities (especially Fire Department). Possible overflow of liquid into the tank to prepare for future recycling or treatment, or to dispose of a small amount of overflow to handle the overflow of liquid.
Part seven----Handling and storage
Handling Precautions: gently. Keep away from sources of ignition.
Storage: 1 independent placed in a well-ventilated area; 2 non fireworks; workshop maintain good ventilation; take measures to prevent static electricity;
Part eight ---Exposure controls /personal protection
Engineering Controls: work site installation of ventilation facilities, maintaining good ventilation;
Respiratory protection: at least wear activated carbon utensils, conditions, wear self-absorption filter respirators (half-mask);
Eye protection: general need special protection;
Physical protection: wear overalls;
Hand protection: Wear protective gloves general operations;
Other protection: no smoking scene. Avoid long-term repeated exposure.
Part nine---Physical and chemical properties
Item |
Specifications |
Appearance |
Slight yellow transparent liquid |
Molecular Weight |
582 |
Solid Content |
96%±2% |
Amine value(mg KOH/g) |
189-193 |
Amine Equivalent(g/mol) |
290 |
Hydroxyl value Equivalent |
5.84 |
Viscosity mpa.s/25℃ |
1000~1500 |
Relative density(25℃) |
1.06±0.02 |
Flash Point(/℃) |
97 |
Main purpose: polyurea coating (waterproof paint levels, high durability, high corrosion resistant paint finish) formulation of the main resin
Part ten--- Stability and reactivity
Stability: The storage period of one year after the shelf life testing qualified, can still be used.
Materials to avoid: acids, acid chlorides, acid anhydrides, strong oxidizing agents, isocyanates.
Part eleven ---Toxicological information
Information on toxicological effects
Acute toxicity, oral:
Aspartic Acid,N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
LD50 rat: > 2.000 mg/kg
Method: Directive 67/548/EEC, Annex V, B.1.
Acute toxicity, dermal:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
LD50 rat: > 2.000 mg/kg
Method: Directive 67/548/EEC, Annex V, B.3.
Acute toxicity, inhalation:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
LC50 rat: > 4.224 mg/m3, 4 h
Method: OECD Test Guideline 403
Primary skin irritation:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
rabbit
Result: slight irritant
Method: OECD Test Guideline 404
Primary mucosae irritation:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
rabbit
Result: slight irritant
Method: OECD Test Guideline 405
Sensitisation:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Skin sensitisation according to Magnusson/Kligmann (maximizing test):
Result: In the guinea-pig the product has a sensitising effect.
Method: OECD Test Guideline 406
Respiratory sensitization
Toxicological studies on the product are not yet available.
Subacute, subchronic and prolonged toxicity:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
NOAEL: 1.000 mg/kg
Application Route: Subacute oral toxicity
Species: rat
Dose Levels: 0 - 40 - 200 - 1000 mg/kg
Method: OECD Test Guideline 407
Carcinogenicity:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Toxicological studies on the product are not yet available.
Reproductive toxicity/Fertility:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Toxicological studies on the product are not yet available.
Reproductive toxicity/Teratogenicity:
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
<####>112000018204
DESMOPHEN NH 1520
Version 3.4 Revision Date 05.10.2011 Print Date 06.10.2011>
7/11 BMS_SDS_AU / AU
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Toxicological studies on the product are not yet available.
Genotoxicity in vitro:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Test type: Salmonella/microsome test (Ames test)
Result: No indication of mutagenic effects.
Method: OECD Test Guideline 471
Test type: Chromosome aberration test in vitro
Result: negative
Method: OECD Test Guideline 473
Genotoxicity in vivo:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Test type: Micronucleus test
Species: mouse
Result: negative
Method: OECD Test Guideline 474
Aspiration toxicity:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Based on available data, the classification criteria are not met.
CMR Assessment:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Carcinogenicity: Based on available data, the classification criteria are not met.
Mutagenicity: In vitro an in vivo tests did not show mutagenic effects. On the basis of this data,
the substance is not classified as mutagenic.
Teratogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity/Fertility: Based on available data, the classification criteria are not met.
Toxicology Assessment:
Aspartic Acid, N,N'-[methylenebis(2-methyl-4,1-cyclohexanediyl)]bis-, 1,1',4,4'-tetraethyl ester
Acute effects: Based on available data, the classification criteria are not met.
Sensitization: May cause sensitization by skin contact.
Repeated dose toxicity: Based on available data, the classification criteria are not met.
Part twelve---Ecological information
Other harmful effects: the substance on the environment may harm water bodies should be given special attention.
Part thirteen --- Disposal consideration
Recommendation: Waste disposal methods: disposal by incineration.
Incinerators emit oxides through the scrubber to remove.
Part fourteen ---Transportation information
Packaging: plastic or iron container seal costumes.
Transport Note: rail transport should be strictly in accordance with the table of dangerous goods in the Ministry of Railway Transport of Dangerous Goods Rules equipped. FOB packaging to complete loading should be safe. To ensure that the container does not leak, it did not fall, do not fall, do not damage during transport. Tank (tank) used in transport vehicles should be grounded chain tank located hole spacer to reduce static electricity shock. Non-mixed with acids, food chemicals shipped.
Part fifteen--- Regulatory information
Regulatory Information: Chemical Dangerous Goods Safety Management Regulations (February 17, 1987 issued by the State Council), the dangerous chemicals Security Implementation Rules (of labor [1992] No. 677), the safe use of chemicals in the workplace regulations ([1996] Ministry of Labor No. 423) and other laws and regulations for the safe use of hazardous chemicals, production, storage, transport, handling and other aspects have made the corresponding provisions; commonly used classification and marking of hazardous chemicals (GB 13690-92) the material designated 8.2 class alkaline corrosive substances.
Part sixteen ---Other information
References: 1. Safety management for chemicals at working spot
2. Safety handbook for hazardous goods
3. All-round book for safety technology hazardous chemicals
4. Register regulation for hazardous chemicals
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.
1.�Jp;��@�er regulation for hazardous chemicals
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.